5. Olga Kurylenko

Another model who successfully crossed into the movie world, Olga Kurylenko was cast as Bond Girl in 2008, joining one very exclusive club. She played the character of Camilla Montes in the James Bond film Quantum of Solace, proving without a shadow of doubt that Bond gets to hang around with the sexiest women out there. The former model has also appeared in other high profile movies such as Oblivion, in which she starred alongside Tom Cruise, and in The November Man, joining former James Bond actor Pierce Brosnan on the set.

Olga Kurylenko also appeared in the video game movie Hitman way back in 2007. Those who have played the games know that the plot follows the exploits of the cold-blooded killer Agent 47. In the movie, he finds himself in the middle of a political conspiracy, as both the Russian military and Interpol are after his hide. But fortunately he gets to spend most of the movie with Nika (played by Olga Kurylenko) whose eye-popping curves make the hitman’s troubles more bearable.